Change the location of the TEMPDB

Use the ALTER DATABASE statement, specifying the logical file name as follows:

use master
go
Alter database tempdb modify file (name = tempdev, filename = 'E:\Sqldata\tempdb.mdf')
go
Alter database tempdb modify file (name = templog, filename = 'E:\Sqldata\templog.ldf')
go

You should receive the following messages that confirm the change:
Message 1
File 'tempdev' modified in sysaltfiles. Delete old file after restarting SQL Server.
Message 2
File 'templog' modified in sysaltfiles. Delete old file after restarting SQL Server.
Using sp_helpfile in tempdb will not confirm these changes until you restart SQL Server.
Stop and then restart SQL Server